Highly efficient CW laser operation in 4 at. % Tm3+ and 4 at. % Y3+ codoped CaF2

Tm:CaF2 and Tm,Y:CaF2 single crystals were prepared by the temperature gradient technique. The spectral properties of Tm,Y:CaF2 single crystals were investigated and compared with those of Tm:CaF2. It was demonstrated that codoping with Y3+ ions could efficiently improve the spectroscopic properties